It is, however, unstable in the thermodynamic sense with a positive enthalpy of formation of +460 kJ mol−1. {[Me3Si)2N]2S} is prepared by the reaction of lithium bis(trimethylsilyl)amide and SCl2. Answer: Tetrasulfur Dinitride S4N2. The first element of this molecule is Se, so, its name is written first. Most English definitions are provided by WordNet . This gold-poppy coloured solid is the most important binary sulfur nitride, which are compounds that contain only the elements sulfur and nitrogen. [1], S4N4 has been shown to co-crystallize with benzene and the C60 molecule. Molar mass of S4N4 = 184.2868 g/mol. In the conversion, the silver first becomes sulfided, and the resulting Ag2S catalyzes the conversion of the S4N4 into the four-membered ring S2N2, which readily polymerizes. Key: LTPQFVPQTZSJGS-UHFFFAOYSA-N Y, Tetrasulfur tetranitride is an inorganic compound with the formula S4N4. Small quantities (less than one gram) deflagrate with a poof and larger sizes will detonate. (1963). The reaction of [Pt2Cl4(PMe2Ph)2] with S4N4 is reported to form a complex where a sulfur forms a dative bond to the metal, this compound upon standing is isomerised to a complex in which a nitrogen atom forms the additional bond to the metal centre. (chemistry) The allotrope of sulfur, S4 having four atoms in a ring. Villena-Blanco, M.; Jolly, W. L.; Egan, B. [1] Purer samples tend to be more explosive. Get XML access to fix the meaning of your metadata. The molecular formula for Tetrasulfur Tetranitride is S4N4. Xenon Hexafluoride Selenium Dichloride Silicon Tetrachloride Arsenic Pentafluoride Dinitrogen Tetroxide Tetrasulfur Tetranitride Disulfur Heptoxide Carbonic Acid Give The Name … Many important S-N compounds are prepared from S4N4. Log Octanol-Water Partition Coef (SRC): Log Kow (KOWWIN v1.67 estimate) = 2.63 Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPWIN v1.42): Boiling Pt (deg C): 655.53 (Adapted Stein & Brown method) Melting Pt (deg C): 285.25 (Mean or Weighted MP) VP(mm Hg,25 deg C): 3.34E-015 (Modified Grain … It also contains nitride ions. It is a precursor to many S-N compounds and has attracted wide interest for its unusual structure and bonding.[1][2]. Because one of its decomposition products is a gas, S4N4 is an explosive. [1] The bonding in S4N4 is considered to be delocalized, which is indicated by the fact that the bond distances between neighboring sulfur and nitrogen atoms are almost the same. References The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following. With a SensagentBox, visitors to your site can access reliable information on over 5 million pages provided by Sensagent.com. Bojes, J.; Chivers, T; Oakley, R. D.; Rauchfuss, T. B.; Gammon, S. (1989). Predicted data is generated using the US Environmental Protection Agency’s EPISuite™. Microsoft Internet Explorer 6.0 does not support some functions on Chemie.DE. Find out how LUMITOS supports you with online marketing. [8], Passing gaseous S4N4 over silver metal yields the low temperature superconductor polythiazyl or polysulfurnitride (transition temperature (0.26±0.03) K[9]), often simply called "(SN)x." In this molecule number of Se is one and O is 2. The SI base unit for amount of substance is the mole. ○   Lettris [14][15] In addition, adducts of aluminium chloride with Se2N2 have been isolated; this is formed from Se4N4.[16]. S4N4 is stable to air. Formula/name Common name Other names Notes S 2: disulfur: A diatomic gas with a triplet ground state like dioxygen. It may not have been reviewed by professional editors (see full disclaimer), All translations of Tetrasulfur tetranitride. Read what you need to know about our industry portal chemeurope.com. 0 1 2 It is protonated by HBF4 to form a tetrafluoroborate salt: The soft Lewis acid CuCl forms a polymer containing intact S4N4 rings as the bridging ligands:[1], S4N4 is sensitive to hydrolysis in the presence of base. ○   Anagrams [11][12] In addition, adducts of aluminium chloride with Se2N2 have been isolated, this is formed from Se4N4.[13]. ○   Wildcard, crossword The nature of the "transannular" S-S interactions is a matter of debate and computational investigation but has been explained in the context of molecular orbital theory. The wordgames anagrams, crossword, Lettris and Boggle are provided by Memodata. Weight calculation: 32.065 * 4 ›› Percent composition by element Mol from pale yellow below −30 °C orange... Binary sulfur nitride, which are compounds that contain only the elements sulfur and.... Small samples can be viewed as a derivative of a hypothetical eight-membered ring of sulfur. 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D. ; Donohue, J curious tetris-clone game where all the bricks the..., etc Boggle are provided by Memodata derivative of a hypothetical eight-membered ring of alternating sulfur nitrogen! So2Cl2 to form S4N4 kJ mol−1 trithionate: [ 1 ], W. L. ; Egan, B |. [ ( Me3Si ) 2N ] 2S as a precursor with pre-formed S–N bonds −ox by adding −ide 178°... Deep red above 100 °C with an accout for my.chemeurope.com you can into... For very simple compositions, such as SbCl5 and SO3 is a gas, S4N4 been. To use all the bricks have the same square shape but different content Litvinov, A. M. Z. ;,... Element is oxygen and it is an inorganic compound with the formula for each of elements. With D2d point group symmetry is distorted in these adducts, thus delocalization electrons. Professional editors ( see from ideas to words ) in two languages to learn more for each of chemical. Sulfuric Acid '' a precursor with pre-formed S-N bonds million pages provided by Memodata NaOH hydrolyzes S4N4 as:... 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Seo2 - selenium dioxide S4N4 - Tetrasulfur tetranitride - Similar structures search, synonyms,,... ( trimethylsilyl ) amide and SCl2, Lettris and Boggle are provided by companies to ECHA in REACH no. Exhibits … molecular formulas because these compounds pages are assembled and adapted from the literature! A precursor with pre-formed S–N bonds hazards have been reviewed by professional editors ( see full disclaimer ) all. To co-crystallize with benzene and the C60 check the results 1992 ) SensagentBox, visitors to your site can reliable! Information ( full-content of Sensagent ) triggered by double-clicking any word on your webpage ) two!

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